Synthetic Route of 76-37-9, As an important bridge between the micro and macro material world, chemistry is one of the main methods and means for humans to understand and transform the material world. 76-37-9, Name is 2,2,3,3-Tetrafluoropropan-1-ol, SMILES is OCC(F)(F)C(F)F, belongs to benzoxazole compound. In a article, author is Segovia-Perez, Raul, introduce new discover of the category.
Coordination diversity in tin compounds with bis(benzoxazole)phenol as a polydentate ligand: Synthesis and crystal structure studies
The reaction of 2,6-bis(benzoxazolyl)-4-tert-butylphenol (HL) with [(BuxSnCl4-x)-Bu-n] (x = 0, 1) in 1:1 stoichiometry yielded the tin coordination complexes [(HL)(SnBuxCl4-x)-Bu-n] [x = 0 (1); x = 1 (2)]. Deprotonation of HL was performed using reagents having groups with high basicity such as (BuLi)-Bu-n or [Sn{N(SiMe3)(2)}(2)]. These basic reagents prompted the coordination of the ligand in its anionic form, yielding the complexes [(thf)(2)Li(L)SnCl4] (3) and [(L)Sn{N(SiMe3)(2)}] (4), respectively. The molecular structure of HL displayed an intramolecular hydrogen bond OH-N and a planar arrangement of the bis(benzoxazolyl)phenolic system. In the molecular structures of both complexes containing HL an intramolecular hydrogen bond of NH-O type was also present. The coordination of the ligand in either neutral or anionic form is described by a kappa O,kappa N chelate mode toward Sn. All complexes displayed bis(benzoxazolyl)phenolic moieties close to planar; the least planar system was observed in 4 that was also studied by DFT methods. [GRAPHICS] .
Synthetic Route of 76-37-9, Because enzymes can increase reaction rates by enormous factors and tend to be very specific, typically producing only a single product in quantitative yield, they are the focus of active research.you can also check out more blogs about 76-37-9.
Reference:
Benzoxazole – Wikipedia,
,Benzoxazole | C7H5NO – PubChem