Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels. 14814-09-6, Name is 3-Mercaptopropyltriethoxysilane, molecular formula is C9H22O3SSi. In an article, author is Yao, Zhenyu,once mentioned of 14814-09-6, Computed Properties of C9H22O3SSi.
Phosphine-phosphonium ylides as ligands in palladium-catalysed C-2-H arylation of benzoxazoles
As balanced electron-rich P,C-chelating ligands, phosphine-phosphonium-ylides are considered for their ability to in situ promote palladium-catalysed direct C(sp(2))-H arylation. Using methyl phosphonium salts of 2,2′-bis(diphenylphosphino)-1,1′-binaphtyl (methyl-BINAPIUM) as ylide precursors under optimized reaction conditions, arylation of benzoxazole was found to proceed in moderate to high yield to give functional 2-aryl benzoxazoles. A strong anion effect of the non-salt free ylide was evidenced (TfO > I > PF6 approximate to salt-free). This first example of phosphonium ylides as ligands in catalytic C-H activation extends the prospect of their general implementation in homogeneous transition metal catalysis. (C) 2020 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
If you¡¯re interested in learning more about 14814-09-6. The above is the message from the blog manager. Computed Properties of C9H22O3SSi.
Reference:
Benzoxazole – Wikipedia,
,Benzoxazole | C7H5NO – PubChem