Reference of 409071-16-5, Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. 409071-16-5, Name is Lithium difluoro(oxalato)borate, SMILES is O=C(O[B-](F)(F)O1)C1=O.[Li+], belongs to benzoxazole compound. In a article, author is Kennedy, Aaron D. W., introduce new discover of the category.
Visible-Light Photoswitching by Azobenzazoles
Three visible-light responsive photoswitches are reported, azobis(1-methyl-benzimidazole) (1), azobis(benzoxazole) (2) and azobis(benzothiazole) (3). Photostationary distributions are obtained upon irradiation with visible light comprising approximately 80 % of the thermally unstable isomer, with thermal half-lives up to 8 min and are mostly invariant to solvent. On protonation, compound 1H(+) has absorption extending beyond 600 nm, allowing switching with yellow light, and a thermal half-life just under 5 minutes. The two isomers have significantly different pK(a) values, offering potential as a pH switch. The absorption spectra of 2 and 3 are insensitive to acid, although changes in the thermal half-life of 3 indicate more basic intermediates that significantly influence the thermal barrier to isomerization. These findings are supported by high-level ab initio calculations, which validate that protonation occurs on the ring nitrogen and that the Z isomer is more basic in all cases.
Reference of 409071-16-5, One of the oldest and most widely used commercial enzyme inhibitors is aspirin, which selectively inhibits one of the enzymes involved in the synthesis of molecules that trigger inflammation. you can also check out more blogs about 409071-16-5.
Reference:
Benzoxazole – Wikipedia,
,Benzoxazole | C7H5NO – PubChem