New research progress on 530-62-1 in 2021.Chemistry is a science major with cience and engineering. The main research directions are chemical synthesis, new energy materials, preparation and modification of special coatings. 530-62-1, Name is Di(1H-imidazol-1-yl)methanone, molecular formula is , belongs to benzoxazole compound. In a document, author is Nicasio-Collazo, Juan, Quality Control of Di(1H-imidazol-1-yl)methanone.
Herein, three novel Pt(II) complexes with formula [trans-Pt(Br-PyBenz-X)(Cl)(2)(DMSO)] (1-3) having Br-pyridylbenz-(imida, oxa or othia)-zole (L1-3) derivatives as potential bidentate ligands, under an unusual kappa(1)-N-coordination mode are reported. All compounds were obtained straightforwardly via reaction of corresponding LPB1-3 and [Pt(Cl)(2)(DMSO)(2)] (DMSO = dimethyl sulfoxide), at 100 degrees C in acetonitrile, respectively. 1-3 complexes were characterized by analytical and spectroscopic data: melting point, FT-IR, Raman, UV/Vis and NMR experiments. Cyclic voltammetry studies show an irreversible two-electron process at -0.50 and -0.51 V, which was ascribed to the Pt(II)/Pt(IV) couple, for complexes 2 and 3. The crystal structure of complex 2 was elucidated by single-crystal X-ray diffraction, where the platinum atom exhibits a square plane geometry, where L-PB2 adopts an unusual mono-coordinated mode via an N-kappa(1)-benzoxazole ring. According to DFT calculations the first N-coordination exchanging one DMSO molecule is favourable, while the second N-coordination is highly impeded.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions. you can also check out more blogs about 530-62-1. Quality Control of Di(1H-imidazol-1-yl)methanone.
Reference:
Benzoxazole – Wikipedia,
,Benzoxazole | C7H5NO – PubChem