New discoveries in chemical research and development in 2021. The transformation of simple hydrocarbons into more complex and valuable products has revolutionised modern synthetic chemistry. In an article, author is Dong, Liangliang, once mentioned the application of 307-24-4, Application of 307-24-4, Name is Undecafluorohexanoic acid, molecular formula is C6HF11O2, molecular weight is 314.0534, category is benzoxazole. Now introduce a scientific discovery about this category.
Mixed-matrix membrane (MMM) is an effective way to overcome trade-off limitations of conventional polymeric membranes. However, the existence of defect voids at the polymer/filler interface often limits their performance improvement. Similar issues are also present in thermally rearranged polybenzoxazole (TR-PBO)-derived MMMs. To address this challenge, the selection of fillers is of great importance. Herein, a novel organic porous nanosphere (TC-cPSB), which is prepared by the polycondensation of 9,9-bis(4-aminophenyl) fluorene (BAFL) and terephthalaldehyde (TPAL) followed by thermal crosslinking, is chosen to engineer the polymer/filler interface. Benefiting from strong intermolecular interaction (pi-pi stacking and hydrogen bonding), the TC-cPSB nanosphere can well disperse in TR-PBO matrix with a defect-free interface. With an increase in TC-cPSB loading, well-designed MMMs exhibit a significant anti-trade-off’ phenomenon whereby gas permeability and selectivity increase simultaneously, following the trend predicted by the Maxwell model. Compared with TR-PBO membrane, the MMM containing 15 wt% of nanosphere shows an increase of 282% and 217.6% in H-2/CO2 selectivity and H-2 permeability, respectively, which is far beyond 2008 Robeson upper bound.
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Reference:
Benzoxazole – Wikipedia,
,Benzoxazole | C7H5NO – PubChem