The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: 1,4,7,10,13-Pentaoxa-16-azacyclooctadecane(SMILESS: O1CCOCCOCCOCCOCCNCC1,cas:33941-15-0) is researched.Application of 36620-11-8. The article 《Alkali metal cation effects on electrocatalytic CO2 reduction with iron porphyrins》 in relation to this compound, is published in Chinese Journal of Catalysis. Let’s take a look at the latest research on this compound (cas:33941-15-0).
The electrocatalytic CO2 reduction reaction (CO2RR) has attracted increasing attention in recent years. Practical electrocatalysis of CO2RR must be carried out in aqueous solutions containing electrolytes of alkali metal cations such as sodium and potassium. Although considerable efforts have been made to design efficient electrocatalysts for CO2RR and to investigate the structure-activity relationships using mol. model complexes, only a few studies have been investigated the effect of alkali metal cations on electrocatalytic CO2RR. In this study, we report the effect of alkali metal cations (Na+ and K+) on electrocatalytic CO2RR with Fe porphyrins. By running CO2RR electrocatalysis in DMF (DMF), we found that the addition of Na+ or K+ considerably improves the catalytic activity of Fe chloride tetrakis(3,4,5-trimethoxyphenyl)porphyrin (FeP). Based on this result, we synthesized an Fe porphyrin N18C6-FeP bearing a tethered 1-aza-18-crown-6-ether (N18C6) group at the second coordination sphere of the Fe site. We showed that with the tethered N18C6 to bind Na+ or K+, N18C6-FeP is more active than FeP for electrocatalytic CO2RR. This work demonstrates the pos. effect of alkali metal cations to improve CO2RR electrocatalysis, which is valuable for the rational design of new efficient catalysts.
From this literature《Alkali metal cation effects on electrocatalytic CO2 reduction with iron porphyrins》,we know some information about this compound(33941-15-0)Application of 33941-15-0, but this is not all information, there are many literatures related to this compound(33941-15-0).
Reference:
Benzoxazole – Wikipedia,
Benzoxazole | C7H5NO – PubChem