Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 3194-15-8, is researched, SMILESS is O=C(C1=CC=CO1)CC, Molecular C7H8O2Journal, Article, Research Support, Non-U.S. Gov’t, Journal of the American Chemical Society called CpRu(PN) Complex-Catalyzed Isomerization of Allylic Alcohols and Its Application to the Asymmetric Synthesis of Muscone, Author is Ito, Masato; Kitahara, Sachiko; Ikariya, Takao, the main research direction is allylic alc isomerization stereoselective ruthenium catalyzed.Recommanded Product: 1-(Furan-2-yl)propan-1-one.
Highly efficient isomerization of allylic alcs. into saturated carbonyls is accomplished using the catalyst system of Cp*RuCl[Ph2P(CH2)2NH2-κ2-P,N]-KOt-Bu (Cp* = η5-C5(CH3)5) under mild conditions. Mechanistic consideration based on isotope-labeling experiments indicated the present reaction is applicable to the asym. isomerization of racemic sec-allylic alcs. with a prochiral olefin via dynamic kinetic resolution A concise asym. synthesis of muscone has been achieved, where the asym. isomerization using an optically active ligand is a key reaction.
From this literature《CpRu(PN) Complex-Catalyzed Isomerization of Allylic Alcohols and Its Application to the Asymmetric Synthesis of Muscone》,we know some information about this compound(3194-15-8)Recommanded Product: 1-(Furan-2-yl)propan-1-one, but this is not all information, there are many literatures related to this compound(3194-15-8).
Reference:
Benzoxazole – Wikipedia,
Benzoxazole | C7H5NO – PubChem