Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Article, Chemical Communications (Cambridge, United Kingdom) called Enantioselective aryl-aryl coupling facilitated by chiral binuclear gold complexes, Author is Himmelstrup, Jonas; Buendia, Mikkel B.; Sun, Xing-Wen; Kramer, Soeren, which mentions a compound: 503538-69-0, SMILESS is FC1(F)OC2=CC=C(P(C3=CC=CC=C3)C4=CC=CC=C4)C(C5=C6OC(F)(F)OC6=CC=C5P(C7=CC=CC=C7)C8=CC=CC=C8)=C2O1, Molecular C38H24F4O4P2, Recommanded Product: 503538-69-0.
Herein, we report stoichiometric investigations embodying the first highly enantioselective aryl-aryl coupling facilitated by a gold complex. With up to 91% ee, this is the first demonstration of a transmetalation and C(sp2)-C(sp2) reductive elimination sequence with high enantioselectivity using a gold complex. The results offer a basis for development of enantioselective gold-catalyzed aryl-aryl coupling reactions.
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Reference:
Benzoxazole – Wikipedia,
Benzoxazole | C7H5NO – PubChem