Application of 6797-13-3. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: 2-Ethylbenzo[d]oxazole, is researched, Molecular C9H9NO, CAS is 6797-13-3, about Catalytic synthesis of oxygen- and nitrogen-containing heterocycles on heterogeneous catalysts.
The Cu-Al2O3- or V2O5-Al2O3-catalyzed reaction of aromatic nitro compounds with primary alcs. was studied and its possible mechanism discussed. PhNO2 (I) treated with MeOH gave predominantly PhNH2 (II), PhNHMe, and PhNMe2 whereas with EtOH 30-40% quinaldine was formed together with II. Similarly, quinolines were formed with PrOH, BuOH, and 2-phenylethanol (III). III gave good yields of 2-benzyl-3-phenylquinoline. The reaction of I with 2-propanol and secondary butanols gave II and the corresponding ketones. I with PhCH2OH yielded, depending on the molar ratio, either II and BzH (nearly stoichiometrical amount at the 1:3 ratio, resp.) or some 2-phenylbenzoxazole (at the 1:6 ratio). Similarly, 2-nitrophenol and primary alcs. gave the corresponding 2-substituted benzoxazoles in good yields. -Nitroanilines or o-dinitrobenzene treated with primary alcs. analogously gave the corresponding substituted benzimidazoles. 0 references
After consulting a lot of data, we found that this compound(6797-13-3)Application of 6797-13-3 can be used in many types of reactions. And in most cases, this compound has more advantages.
Reference:
Benzoxazole – Wikipedia,
Benzoxazole | C7H5NO – PubChem