Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. In an article, author is Mandapati, Pavan, once mentioned the application of 583-55-1, Name is 1-Bromo-2-iodobenzene, molecular formula is C6H4BrI, molecular weight is 282.9, MDL number is MFCD00001030, category is benzoxazole. Now introduce a scientific discovery about this category, Category: benzoxazole.
Catalytic C-H Bond Alkylation of Azoles with Alkyl Halides Mediated by Nickel(II) Complexes of Phenanthridine-Based N boolean AND N-boolean AND N Pincer Ligands
Ni(II) complexes supported by tridentate (NN-boolean AND N)-N-boolean AND diarylamido pincer-type ligands have been demonstrated to act as active catalysts in the carbon-carbon bond forming alkylation of azoles using unactivated alkyl halides. Here, we show that benzannulated phenanthridine-containing ligands can form homogeneous Ni(II) catalysts active with both benzoxazole and benzothiazole substrates. These precatalysts have been fully characterized in solution and the solid state, including by cyclic voltammetry.
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Reference:
Benzoxazole – Wikipedia,
,Benzoxazole | C7H5NO – PubChem