Archives for Chemistry Experiments of 5-Fluorobenzo[d]oxazol-2(3H)-one

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Synthetic Route of 13451-79-1. In my other articles, you can also check out more blogs about 13451-79-1

Synthetic Route of 13451-79-1, A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 13451-79-1, Name is 5-Fluorobenzo[d]oxazol-2(3H)-one, molecular formula is C7H4FNO2. In a Article£¬once mentioned of 13451-79-1

Rhodium(II)-Catalyzed Undirected and Selective C(sp2)-H Amination en Route to Benzoxazolones

Rhodium(II) can effectively promote the activation and cyclization of arylcarbamate substrates to yield benzoxazolones via an intramolecular nitrene C-H insertion reaction. Investigation of the substrate scope shows that the reaction undergoes selective aromatic C(sp2) – H amination over more labile o-C(sp3) – H bonds. Observation of inverse secondary KIE (PH/PD = 0.42 ¡À 0.03) indicates involvement of aromatic electrophilic substitution mechanism for this aryl C-H amidation transformation.

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Synthetic Route of 13451-79-1. In my other articles, you can also check out more blogs about 13451-79-1

Reference£º
Benzoxazole – Wikipedia,
Benzoxazole | C7H5NO – PubChem