122433-29-8, Name is 1-(Benzo[d]oxazol-2-yl)ethanone, belongs to benzoxazole compound, is a common compound. Computed Properties of C9H7NO2In an article, once mentioned the new application about 122433-29-8.
The Synthesis and Configurational Stability of Differentially Protected beta-Hydroxy-beta-amino Aldehydes
Syntheses of 1,1-dimethylethyl (S)-4-formyl-2,2-dimethyl-3-oxazolidinecarboxylate (5) and 1,1-dimethylethyl (4S-trans)-4-formyl-2,2,5-trimethyl-3-oxazolidinecarboxylate (6) from commercially available serine and threonine derivatives are described.The method involves selective reduction of the corresponding oxazolidine esters 3 and 4 using diisobutylaluminum hydride at low temperature.These differentially protected beta-hydroxy-alpha-amino aldehydes are also shown to be produced in 93-95 percent enantiomeric excess (via NMR and HPLC analysis of the Mosher esterderivatives 8 and epi-8)-thus making them useful as chiral, nonracemic synthons for asymmetric synthesis.
Do you like my blog? If you like, you can also browse other articles about this kind. Thanks for taking the time to read the blog about 122433-29-8
Reference£º
Benzoxazole – Wikipedia,
Benzoxazole | C7H5NO – PubChem