Chemistry is traditionally divided into organic and inorganic chemistry. The former is the study of compounds containing at least one carbon-hydrogen bonds. 76-37-9, Name is 2,2,3,3-Tetrafluoropropan-1-ol, molecular formula is C3H4F4O, belongs to benzoxazole compound, is a common compound. In a patnet, author is Ge, Bailu, once mentioned the new application about 76-37-9, Application In Synthesis of 2,2,3,3-Tetrafluoropropan-1-ol.
Acid-promoted cleavage of the C-C double bond of N-(2-Hydroxylphenyl)enaminones for the synthesis of benzoxazoles
An acid-mediated selective cleavage of C-C double bond of N-(2-hydroxylphenyl)enaminones with formation a new C-O bond for the synthesis of 2-substituted benzoxazoles has been developed. This protocol proceeds under transition metal- and oxidant-free conditions with broad functional group tolerance. The oxidative cleavage of C-C double bond of N-(2-hydroxylphenyl)enaminone is also realized using NCS or NFSI as oxidants with release of 2,2-dihalogen-acetophenone fragments. (C) 2019 Elsevier Ltd. All rights reserved.
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Reference:
Benzoxazole – Wikipedia,
,Benzoxazole | C7H5NO – PubChem