Chemistry is traditionally divided into organic and inorganic chemistry. The former is the study of compounds containing at least one carbon-hydrogen bonds. 363-72-4, Name is Pentafluorobenzene, molecular formula is C6HF5, belongs to benzoxazole compound, is a common compound. In a patnet, author is Wu, Huilu, once mentioned the new application about 363-72-4, Quality Control of Pentafluorobenzene.
Synthesis, structure, luminescence and electrochemical and antioxidant properties of anion-controlled silver(I) complexes with 2,2 ‘-(1,4-butanediyl)bis-1,3-benzoxazole
To explore the influence of various anions on the self-assembly and properties of silver complexes, reactions of anions of silver salts with 2,2 ‘-(1,4-butanediyl)bis-1,3-benzoxazole (BBO) afforded four complexes, formulated as [Ag-2(BBO)(2)(p-toluenesulfonate)(2)] (1), {[Ag(BBO)(picrate)]}(infinity) (2), {[Ag(BBO)(1/2)(o-coumarate)]center dot DMF}(infinity) (3) and {[Ag-2(BBO)(3)](PF6)(2)}(infinity) (4). These complexes were characterized using elemental analysis, infrared spectroscopy and single-crystal X-ray diffraction. The crystal analysis results show that under the influence of coordination modes and steric hindrance of anions, the complexes exhibited binuclear (1), one-dimensional polymeric (2 and 3) and two-dimensional polymeric (4) structures. Compared with the BBO ligand, only complex 1 has a new emission peak at 428 nm, which is attributed to ligand-metal charge transfer. The emission peaks of complexes 2-4 are similar to those of the BBO ligand, which can be due to pi-pi* and n-pi* transitions. These results indicate that anions can modulate the structures and luminescent properties of silver complexes. Moreover, cyclic voltammograms of 1-4 indicated an irreversible Ag+/Ag couple with the order of reversibility being 2 > 1 > 4 > 3. In vitro antioxidant experiments showed that complex 3 has significant antioxidant activity against superoxide and hydroxyl radicals.
We¡¯ll also look at important developments in the pharmaceutical industry because understanding organic chemistry is important in understanding health, medicine, 363-72-4. The above is the message from the blog manager. Quality Control of Pentafluorobenzene.
Reference:
Benzoxazole – Wikipedia,
,Benzoxazole | C7H5NO – PubChem