Discovery of 13451-79-1

A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 13451-79-1

Electric Literature of 13451-79-1, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.13451-79-1, Name is 5-Fluorobenzo[d]oxazol-2(3H)-one, molecular formula is C7H4FNO2. In a Article£¬once mentioned of 13451-79-1

Iron-Catalyzed Arene C-H Amidation Using Functionalized Hydroxyl Amines at Room Temperature

Herein, we report Fe(III)(TPP)Cl as an effective catalyst for promoting arene C-H amidation through intramolecular cyclization of N-tosyloxyarylcarbamate substrates. The reaction proceeds via nitrene (outer sphere pathway) C(sp2)-H insertion to yield benzoxazolones under external-oxidant-free conditions at ambient temperature. The method is operationally simple and scalable with high-functional-group tolerance. Preliminary experimental and computational data indicates involvement of electrophilic aromatic substitution mechanism for this aryl C-H amidation transformation, distinct from operating mechanism reported previously in aryl C-H amination using azide-based substrates.

A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 13451-79-1

Reference£º
Benzoxazole – Wikipedia,
Benzoxazole | C7H5NO – PubChem