Chemistry can be defined as the study of matter and the changes it undergoes. You¡¯ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology. 75178-96-0, Name is tert-Butyl (3-aminopropyl)carbamate, molecular formula is , belongs to benzoxazole compound. In a document, author is Murata, Yuki, Application In Synthesis of tert-Butyl (3-aminopropyl)carbamate.
Synthesis of 2-(arylsulfenyl)azoles by copper-catalyzed S-arylation of azole-2-thiones with triarylbismuthines
A simple approach for the S-arylation of azole-2-thiones with trivalent organobismuth reagents is described. The reaction of azole-2-thiones containing a heterocyclic ring (benzothiazole, benzoxazole, benzimidazole, and pyrimidine) with triarylbismuthines in the presence of CuI (10 mol%) and 1,10-phenanthroline (10 mol%) under aerobic conditions afforded S-arylated coupling products in moderate-to-high yields. Triarylbismuthines gave better results compared to various aryl donors based from other typical elements such as antimony, silicon, tin, and tellurium. This reaction is the first example of the Cu-catalyzed S-arylation of azole-2-thiones using an organobismuth compound.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 75178-96-0, in my other articles. Application In Synthesis of tert-Butyl (3-aminopropyl)carbamate.
Reference:
Benzoxazole – Wikipedia,
,Benzoxazole | C7H5NO – PubChem