Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels. 372-38-3, Name is 1,3,5-Trifluorobenzene, molecular formula is C6H3F3. In an article, author is Liu, Mingyang,once mentioned of 372-38-3, Computed Properties of https://www.ambeed.com/products/372-38-3.html.
Transformation of aryl alcohols into high-value functionalized aromatic compounds by selective cleavage and functionalization of the C(aryl)-C(OH) bond is of crucial importance, but very challenging by far. Herein, for the first time, we report a novel and versatile strategy for activation and functionalization of C(aryl)-C(OH) bonds by the cooperation of oxygenation and decarboxylative functionalization. A diverse range of aryl alcohol substrates were employed as arylation reagentsviathe cleavage of C(aryl)-C(OH) bonds and effectively converted into corresponding thioether, arene, and arylated benzoxazole products in excellent yields, in a Cu based catalytic system using O(2)as the oxidant. This study offers a new way for aryl alcohol conversion and potentially offers a new opportunity to produce high-value functionalized aromatics from renewable feedstocks such as lignin which features abundant C(aryl)-C(OH) bonds in its linkages.
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Reference:
Benzoxazole – Wikipedia,
,Benzoxazole | C7H5NO – PubChem