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Visible-Light-Induced Decarboxylative C-H Adamantylation of Azoles at Ambient Temperature
The visible-light-promoted oxidant-free decarboxylative C-H adamantylation of azoles was accomplished under ambient reaction conditions. The novel acridinium photocatalyst and cobalt synergistic catalysis enabled the C-H adamantylation under oxidant-free reaction conditions. This C-H adamantylation strategy proved viable for a wide range of substituted azoles, including benzothiazole, benzoxazole, and benzimidazoles as well as caffeine derivatives, providing an expedient access to 2-adamantyl-substituted azoles.
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Reference:
Benzoxazole – Wikipedia,
,Benzoxazole | C7H5NO – PubChem