Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. In an article, author is Wang, Kezhou, once mentioned the application of 2892-51-5, Name is 3,4-Dihydroxy-3-cyclobutene-1,2-dione, molecular formula is C4H2O4, molecular weight is 114.06, MDL number is MFCD00001334, category is benzoxazole. Now introduce a scientific discovery about this category, Recommanded Product: 2892-51-5.
Enantioselective Reaction between 2-(Cyanomethyl)azaarenes and N-Boc-amino Sulfones
A series of 2-(cyanomethyl)azaarenes containing benzothiazole or benzoxazole were designed and synthesized for asymmetric alpha-functionalization with N-Boc-amino sulfones. The Mannich adducts were obtained in high yields with good diastereo- and enantioselectivities. Aryl substituted amino sulfones were tolerated under the current conditions, and the reaction can be performed on gram scale in good results.
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Reference:
Benzoxazole – Wikipedia,
,Benzoxazole | C7H5NO – PubChem