Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels. 136630-39-2, Name is 2,7-Dibromo-9H-carbazole, molecular formula is C12H7Br2N. In an article, author is Mo, Lingchao,once mentioned of 136630-39-2, Quality Control of 2,7-Dibromo-9H-carbazole.
New negative dielectric anisotropy liquid crystals based on benzofuran core
In this paper, new liquid crystal compounds with negative dielectric anisotropy were synthesised by regulating the substituents on the benzofuran ring. Their structures were confirmed by(1)H-nuclear magnetic resonance,(CNMR)-C-13 and mass spectra. The effects of substituent on the properties of liquid crystals were investigated. Compared with the reference compounds, the compounds with 5-ethoxy-6,7-difluorobenzofuran ring exhibit higher clearing points as well as the tendency of expansion of SmA phase range. The density functional theory calculation results reveal that the 6-ethoxy-7-fluorobenzofuran-based compound has smaller aspect ratio than that of the 5-ethoxy-6,7-difluorobenzofuran-based compound, which results in the diminish of the mesophase. Although the dielectric anisotropy of the 5-ethoxy-6,7-difluorobenzofuran-based compound is slightly lower than that of the reference compound, it has both the largest perpendicular and parallel dielectric constant.
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Reference:
Benzoxazole – Wikipedia,
,Benzoxazole | C7H5NO – PubChem