The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature. 51-67-2, Name is Tyramine, SMILES is C1=C(C=CC(=C1)O)CCN, in an article , author is Oshimoto, Kohei, once mentioned of 51-67-2, Quality Control of Tyramine.
Synthesis of benzoxazoles via the copper-catalyzed hydroamination of alkynones with 2-aminophenols
We describe herein the synthetic method to benzoxazole derivatives via the copper-catalyzed hydroamination of alkynones with 2-aminophenols. The method produced a wide variety of functionalized benzoxazole derivatives in good yields. Preliminary mechanistic experiments revealed that the reaction would proceed through the copper-catalyzed hydroamination of alkynones and the sequential intramolecular cyclization of beta-iminoketones/elimination of acetophenone promoted by the copper catalyst.
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Reference:
Benzoxazole – Wikipedia,
,Benzoxazole | C7H5NO – PubChem