Chemistry is an experimental science, Product Details of 5535-48-8, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 5535-48-8, Name is (Vinylsulfonyl)benzene, molecular formula is C8H8O2S, belongs to benzoxazole compound. In a document, author is Gryaznova, Tatyana, V.
Copper or Silver-Mediated Oxidative C(sp(2))-H/N-H Cross-Coupling of Phthalimide and Heterocyclic Arenes: Access to N-Arylphthalimides
Copper or silver-catalyzed direct C(sp(2))-H/N-H electrochemical cross-coupling of phthalimide and heterocyclic arenes (2-phenylpyridine, benzo[h]quinoline, benzoxazole, and benzothiazole, etc.) for the efficient synthesis of phthalimide derivatives is described. This reaction features good yield, mild conditions, and broad substrate scope, which provides an efficient and straightforward protocol to access this type of tertiary amines. For the first time, the proposed protocol is based not only on a copper catalyst but also on silver, which has never been used for this purpose before, and both give comparable results. Mechanistic investigations (voltammetry, ESR studies) disclosed that a free-radical pathway might be excluded in this process accomplished through Cu(I)/Cu(II)/Cu(III) or Ag(I)/Ag(III) cycles.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 5535-48-8, in my other articles. Product Details of 5535-48-8.
Reference:
Benzoxazole – Wikipedia,
,Benzoxazole | C7H5NO – PubChem