Jiang, Yu-Han; Qiu, Qi-Ming; Jiang, Rui-Xia; Huang, Xu; Jin, Qiong-Hua published the article 《Iodido[5-methyl-1H-benzimidazole-2(3H)-thione-κS]bis(triphenylphosphane-κP)copper(I) methanol monosolvate》. Keywords: mol structure copper iodido methylbenzimidazolethione triphenylphosphine complex methanol solvate; crystal structure copper iodido methylbenzimidazolethione triphenylphosphine complex methanol solvate; hydrogen bond copper iodido methylbenzimidazolethione triphenylphosphine complex methanol solvate.They researched the compound: 2-Mercapto-5-methylbenzimidazole( cas:27231-36-3 ).Quality Control of 2-Mercapto-5-methylbenzimidazole. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:27231-36-3) here.
In the title compound, [CuI(C8H8N2S)(C18H15P)2]·MeOH, the coordination environment around the CuI atom is distorted tetrahedral, defined by two P atoms of two PPh3 ligands, one S atom of a 5-methyl-1H-benzimidazole-2(3H)-thione ligand and one I atom. The complex mols. and the MeOH solvent mols. are connected via N-H···O and O-H···I H bonds, forming a chain along [010]. An intramol. N-H···I H bond is also observed Crystallog. data and at. coordinates are given.
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Reference:
Benzoxazole – Wikipedia,
Benzoxazole | C7H5NO – PubChem