Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics, Recommanded Product: 2-(4-Fluorophenyl)acetic acid, 405-50-5, Name is 2-(4-Fluorophenyl)acetic acid, SMILES is C1=C(C=CC(=C1)F)CC(O)=O, belongs to benzoxazole compound. In a document, author is Katlenok, Eugene A., introduce the new discover.
Supramolecular Assembly of Metal Complexes by (Aryl)I…dz2 [Pt-II] Halogen Bonds
The theoretical data for the half-lantern complexes [{Pt(CN<^>)(mu-SN<^>)}(2)] [1-3; CN<^> is cyclometalated 2-Ph-enzothiazole; SN<^> is 2-SH-pyridine (1), 2-SH-benzoxazole (2), 2-SH-tetrafluorobenzothiazole (3)] indicate that the Pt…Pt orbital interaction increases the nucleophilicity of the outer dz2 orbitals to provide assembly with electrophilic species. Complexes 1-3 were co-crystallized with bifunctional halogen bonding (XB) donors to give adducts (1-3)(2).(1,4-diiodotetrafluorobenzene) and infinite polymeric [1.1,1 ‘-diiodoperfluorodiphenyl](n). X-ray crystallography revealed that the supramolecular assembly is achieved through (Aryl)I…dz2[Pt-II] XBs between iodine sigma-holes and lone pairs of the positively charged (Pt-II)(2) centers acting as nucleophilic sites. The polymer includes a curved linear chain…Pt-2…I(arene(F))I…Pt-2… involving XB between iodine atoms of the perfluoroarene linkers and (Pt-II)(2) moieties. The Pt-195 NMR, UV/Vis, and CV studies indicate that XB is preserved in CH(D)(2)Cl-2 solutions.
A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 405-50-5. Recommanded Product: 2-(4-Fluorophenyl)acetic acid.
Reference:
Benzoxazole – Wikipedia,
,Benzoxazole | C7H5NO – PubChem