Electric Literature of C7H8O2. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: 1-(Furan-2-yl)propan-1-one, is researched, Molecular C7H8O2, CAS is 3194-15-8, about Isomerization of Allylic Alcohols to Ketones Catalyzed by Well-Defined Iron PNP Pincer Catalysts. Author is Xia, Tian; Wei, Zhihong; Spiegelberg, Brian; Jiao, Haijun; Hinze, Sandra; de Vries, Johannes G..
[Fe(PNP)(CO)HCl] (PNP=di-(2-diisopropylphosphanyl-ethyl)amine), activated in situ with KOtBu, is a highly active catalyst for the isomerization of allylic alcs. to ketones without an external hydrogen supply. High reaction rates were obtained at 80 °, but the catalyst is also sufficiently active at room temperature with most substrates. The reaction follows a self-hydrogen-borrowing mechanism, as verified by DFT calculations An alternative isomerization through alkene insertion and β-hydride elimination could be excluded on the basis of a much higher barrier. In alc. solvents, the ketone product is further reduced to the saturated alc.
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Reference:
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