924869-17-0, Name is Methyl benzo[d]oxazole-5-carboxylate, belongs to benzoxazole compound, is a common compound. SDS of cas: 924869-17-0In an article, once mentioned the new application about 924869-17-0.
Cu-Catalyzed Direct C-P Bond Formation through Dehydrogenative Cross-Coupling Reactions between Azoles and Dialkyl Phosphites
A direct dehydrogenative cross-coupling of azoles [C(sp2)-H] with dialkyl phosphites [P(O)-H] to access 2-phosphonated azoles using Cu(I)/Cu(II) as catalyst and K2S2O8/di-tert-butylperoxide as oxidant has been achieved. A remarkable advantage over reported procedures includes that oxazoles, imidazoles, benz(ox/othi/imid)azoles, and indole are found to react under optimized reaction conditions to provide corresponding adducts in high yields. The mechanistic insight of cross-coupling was obtained by deuterium kinetic isotope effect studies.
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Reference£º
Benzoxazole – Wikipedia,
Benzoxazole | C7H5NO – PubChem