Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 3194-15-8, is researched, SMILESS is O=C(C1=CC=CO1)CC, Molecular C7H8O2Journal, Article, Research Support, Non-U.S. Gov’t, Organic Letters called Enantioselective Metal-Free Hydrogenations of Disubstituted Quinolines, Author is Zhang, Zhenhua; Du, Haifeng, the main research direction is quinoline chiral diene derived borane enantioselective diastereoselective hydrogenation catalyst; tetrahydroquinoline stereoselective preparation.Product Details of 3194-15-8.
A metal-free hydrogenation of 2,4-disubstituted quinolines was realized for the first time using chiral diene derived borane catalysts to furnish the corresponding tetrahydroquinolines in 75-98% yields with 95/5-99/1 dr’s and 86-98% ee’s. This catalytic system was also effective for 2,3-disubstituted quinolines to give moderate to good ee’s.
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Reference:
Benzoxazole – Wikipedia,
Benzoxazole | C7H5NO – PubChem