What I Wish Everyone Knew About 1-Bromopyrene

If you are interested in 1714-29-0, you can contact me at any time and look forward to more communication. Recommanded Product: 1-Bromopyrene.

In an article, author is Chernyshov, Vladimir V., once mentioned the application of 1714-29-0, Recommanded Product: 1-Bromopyrene, Name is 1-Bromopyrene, molecular formula is C16H9Br, molecular weight is 281.15, MDL number is MFCD00015767, category is benzoxazole. Now introduce a scientific discovery about this category.

A new ring opening reaction was found while attempting to isolate the imines from ortho-heteroatom substituted anilines and camphor-like bicyclic ketones. The benzoazoles containing a cyclopentanemethyl group at position 2 of the heterocycle were isolated instead of the expected imines. The detailed study of the transformation, including EPR experiments, revealed the most probable radical mechanism. The proposed reaction pathways were confirmed by quantum chemical calculations. The dichotomy of 1-2 and 2-3 bonds cleavage is discussed together with the evaluation of the stereochemical outcome of the reactions. The benzoazoles obtained via the new reaction are of particular interest for the medicinal chemistry.

If you are interested in 1714-29-0, you can contact me at any time and look forward to more communication. Recommanded Product: 1-Bromopyrene.

Reference:
Benzoxazole – Wikipedia,
,Benzoxazole | C7H5NO – PubChem