Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media, causing turnover rates to depend strongly on interfacial structure and composition, 10465-78-8, Name is N1,N1,N2,N2-Tetramethyldiazene-1,2-dicarboxamide, SMILES is O=C(/N=N/C(N(C)C)=O)N(C)C, in an article , author is Xia, Lixian, once mentioned of 10465-78-8, Category: benzoxazole.
Synthesis, structure, fluorescence, and electrochemical properties of a binuclear Ag(I) complex with 1,4-bis benzo[d]oxazol-2-yl)butane as a ligand
Reaction of 1,4-bis(benzo[d]oxazol-2-yl)butane (BBO) with [Ag(CH3CN)(4)(ClO4)] afforded a new binuclear silver(I) complex, with composition [Ag-2(BBO)(2)(ClO4)(2)], characterized by elemental analysis, UV/Vis and IR spectroscopy, and single-crystal X-ray diffraction. The results show that the Ag(I) complex consists of a centrosymmetric dimetallacyclic structure assembled from two Ag(I) atoms and two bridging BBO ligands. The coordination environment of silver(I) complex can be described as distorted trigonal planar, with one oxygen atom from a perchlorate anion and two nitrogen atoms from two BBO ligands. The luminescence properties of the ligand and the Ag(I) complex were studied in the solid state. The emission peaks of the Ag(I) complex are attributed to ligand-centered transitions. There is no effect of the complexation except for a partial quenching. The cyclic voltammograms of the Ag(I) complex indicated an irreversible Ag+/Ag couple.
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Benzoxazole – Wikipedia,
,Benzoxazole | C7H5NO – PubChem