Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. In an article, author is Grebneva, Ekaterina A., once mentioned the application of 345-92-6, Name is Bis(4-Fluorophenyl)methanone, molecular formula is C13H8F2O, molecular weight is 218.2, MDL number is MFCD00000353, category is benzoxazole. Now introduce a scientific discovery about this category, SDS of cas: 345-92-6.
Synthesis and structure of novel Si-substituted silylpropyl derivatives of 2-mercaptobenzoxazole and 2-mercaptobenzothiazole
A previously unknown carbofunctional (trimethoxysilyl)propyl derivative of the 2-mercaptobenzoxazole, C6H4NOCS(CH2)(3)Si(OMe)(3), containing a tetracoordinated silicon atom was synthesized by nucleophilic substitution of the chlorine atom in the (3-chloropropyl)-trimethoxysilane with the benzoxazol-2-ylsulfanyl group. The reaction of 2-[(trimethoxysilyl)propylsulfanyl]benzoxazole or -benzothiazole with boron trifluoride etherate led to a previously unknown hydrolytically unstable Si-fluoropropyl derivatives of 2-mercaptobenzoxazole or 2-mercaptobenzothiazole, C6H4N(Y)CS(CH2)(3)SiF3 (Y = O, S). By transesterification of 2-[(trimethoxysilyl)-propylsulfanyl]benzoxazole by tris(2-hydroxyethyl)amine, a new silatranylpropyl derivative of 2-mercaptobenzoxazole containing an intramolecular coordination bond N -> Si and a pentacoordinated silicon atom, C6H4NOCS(CH2)(3)Si(OCH2CH2)(3)N, was obtained.
Do you like my blog? If you like, you can also browse other articles about this kind. Thanks for taking the time to read the blog about 345-92-6, SDS of cas: 345-92-6.
Reference:
Benzoxazole – Wikipedia,
,Benzoxazole | C7H5NO – PubChem