In 2019 CHEMSUSCHEM published article about CARBON-DIOXIDE HYDROGENATION; FORMIC-ACID; ALKYL FORMATES; METHANOL; COMPLEXES; N,N-DIMETHYLFORMAMIDE; ESTERIFICATION; CHEMICALS; ENERGY in [Sun, Ruiyan; Kann, Anna; Hausoul, Peter J. C.; Palkovits, Regina] Rhein Westfal TH Aachen, Inst Tech & Makromol Chem, Worringerweg 2, D-52074 Aachen, Germany; [Hartmann, Heinrich; Besmehn, Astrid] Forschungszentrum Julich, Zent Inst Engn Elekt & Analyt ZEA 3, D-52425 Julich, Germany in 2019, Cited 40. The Name is 4,4′-Dibromobiphenyl. Through research, I have a further understanding and discovery of 92-86-4. COA of Formula: C12H8Br2
Methyl formate was produced in one pot through the hydrogenation of CO2 to formic acid/formate followed by an esterification step. The route offers the possibility to integrate renewable energy into the fossil-based chemical value chain. In this work, a phosphine-polymer-anchored Ru complex was shown to be an efficient solid catalyst for the direct hydrogenation of CO2 to methyl formate. The 1,2-bis(diphenylphosphino)ethane-like polymer presented the highest activity with a turnover number (TON) of up to 3401 at 160 degrees C. The reaction parameters were systemically investigated to optimize the reaction towards the formation of methyl formate. This catalyst could be reused seven times without a significant decrease in activity. Evolution of the catalytic Ru center during the reaction was revealed, and a possible reaction mechanism was proposed.
About 4,4′-Dibromobiphenyl, If you have any questions, you can contact Sun, RY; Kann, A; Hartmann, H; Besmehn, A; Hausoul, PJC; Palkovits, R or concate me.. COA of Formula: C12H8Br2
Reference:
Benzoxazole – Wikipedia,
,Benzoxazole | C7H5NO – PubChem