I found the field of Chemistry; Science & Technology – Other Topics; Materials Science; Physics very interesting. Saw the article Chiral Liquid-Crystalline Ionic Liquid Systems Useful for Electrochemical Polymerization that Affords Helical Conjugated Polymers published in 2019. Product Details of 92-86-4, Reprint Addresses Akagi, K (corresponding author), Kyoto Univ, Dept Polymer Chem, Kyoto 6158510, Japan.; Akagi, K (corresponding author), Ritsumeikan Univ, Res Org Sci & Technol, Shiga 5258577, Japan.. The CAS is 92-86-4. Through research, I have a further understanding and discovery of 4,4′-Dibromobiphenyl
Ionic liquids bearing both liquid crystallinity and chirality are potentially applicable for chiral electrochemical syntheses and polymerizations. In this study, two types of chiral nematic liquid-crystalline ionic liquids (N*-LCILs) are developed to achieve asymmetric electrochemical polymerization without a supporting electrolyte and even a chiral dopant. N*-LCILs are prepared i) by adding an axially chiral binaphthyl derivative as an external chiral dopant to imidazolium cation-based LCILs or ii) by incorporating a chiral binaphthyl phosphate as a counter anion in LCILs. Helical poly(3,4-ethylenedioxythiophene) (H-PEDOT) films are successfully synthesized through electrochemical polymerization of a dimer- or trimer-type 3,4-ethylenedioxythiophene (EDOT) monomer in an N*-LCIL, where N*-LCIL plays the role of both an asymmetric solvent and a supporting electrolyte. H-PEDOT films have helically pi-stacked structures of conjugated chains and spiral morphologies consisting of one-handed screwed fibril bundles. The plausible mechanism of the asymmetric electrochemical polymerization of EDOT in N*-LCIL is proposed to elucidate the correlation of helical sense between the helically pi-stacked chains, screwed fibril bundles, and N*-LCIL. The two present types of N*-LCILs are the first to enable supporting electrolyte-free asymmetric electrochemical polymerization, and they have potential applications in various types of chiral electrochemical syntheses, expanding the potential utility of ionic liquids.
Product Details of 92-86-4. Welcome to talk about 92-86-4, If you have any questions, you can contact Yamakawa, S; Wada, K; Hidaka, M; Hanasaki, T; Akagi, K or send Email.
Reference:
Benzoxazole – Wikipedia,
,Benzoxazole | C7H5NO – PubChem